These were bound-together remaindered copies of selected DC and Marvel comics with covers taken from original DC comics or sometimes new covers adapted from interior scenes. Very hard to find in Near Mint but often show up on eBay in low and mid grade. Good reading value.
#1 of this title seems to be scarce for some reason. To my knowledge there are 24 different Double Double Comics across a number of titles - Action, Adventure, Batman, Detective, Jimmy Olsen, Lois Lane, Strange Adventures, Superboy, Superman and World's Finest. But I'm still looking!
Note: some PR issues may have no value. Selected issues in FN, VF or VF/NM may not exist in some titles.